Make sure to find the Sad Face icon and flip that over.
The first puzzle requires you to line up the cards in the order they appear in the Bible passage you read. The colors should go, from left to right, Red-Green-Yellow-Blue, while lining up the lines shown in the corners to spell out the numbers 5-3-8. Find that card and flip it over.
The second use for this card comes a bit later when the New Covenant cards come out.